Refinery fractionation columns at dusk with aviation context in the distance

Jet-RCF · Jet-Range Circular Feedstock

JET-RCF
JET RANGE FRACTION ANALYSIS

Identifying and recovering aviation-fuel-range molecules from circular pyrolysis hydrocarbons.

Plastic-derived pyrolysis liquids contain hydrocarbons distributed across a broad molecular and boiling range. Green Fuel Tech's strategy is to use controlled upgrading and fractionation to isolate a targeted jet-range fraction rather than treating the entire pyrolysis liquid as a single fuel product.

This fraction is designated JET-RCF — Jet-Range Circular Feedstock.

Development productREFINERY FEEDSTOCK — NOT FINISHED SAF

JET-RCF ≠ FINISHED SAF

Jet-RCF is a targeted hydrocarbon fraction intended for further analysis, refining, hydrotreatment and potential use as a refinery feedstock toward an aviation-fuel pathway. Green Fuel Tech does not present it as certified Jet A-1 or finished SAF.

Research-based molecular range

WHERE THE JET-RANGE MOLECULES SIT.

Recent plastic-to-jet research identifies C8–C16 as the principal carbon-number window relevant to kerosene-range aviation hydrocarbons.

Light hydrocarbons

< C8

Jet-range target

C8 – C16

Heavier hydrocarbons

> C16

C1C8 — C16 JET-RANGE TARGETC40+

Research target

Approximately C8–C16

Carbon number

However, carbon number alone does not determine aviation-fuel suitability. Molecular structure, branching, aromatic content, olefins, contaminants, freezing behaviour, flash point, energy density and thermal stability are also critical.

Proposed Green Fuel Tech fractionation window

A RESEARCH WINDOW — NOT A FIXED PRODUCTION SPECIFICATION.

Upgraded pyrolysis oil enters the fractionation column. As the column separates by boiling range, a targeted jet-range fraction is drawn off under controlled conditions.

Naphtha / light fraction

≈ < 150–160 °C

Jet-RCF development window

≈ 150–250 °C

Diesel transition range

≈ 250 °C +

UPGRADED PYROLYSIS OILDISTILLATION & FRACTIONATIONLIGHT ENDSNon-condensable / process energyCIRCULAR NAPHTHALight hydrocarbon cutJET-RANGE FRACTION — JET-RCFTargeted jet boiling rangeDIESEL-RANGE FRACTIONMiddle distillateHEAVIER FRACTIONSMarine / industrial fuel rangeLIGHTER ↑HEAVIER ↓

Published pyrolysis-oil fractionation studies commonly identify approximately 150–250 °C as a useful experimental window covering much of the jet/kerosene-range material. Commercial Jet A / Jet A-1 distillation specifications allow a broader overall boiling envelope, with final boiling point controlled at approximately 300 °C. Green Fuel Tech should therefore experimentally optimise the Jet-RCF cut rather than automatically collecting the entire theoretical aviation-fuel boiling envelope.

Initial development cut

150–250 °C

Optimisation window

≈ 160–260 °C

Potential broader evaluation

≈ 150–300 °C

Research / development ranges — not final product specifications

Why the cut point matters

EVERY DEGREE CHANGES THE MOLECULE MIX.

Move the cut from narrow to broad and the balance between selectivity, yield and downstream upgrading effort shifts with it.

Narrow cutBroad cut

ILLUSTRATIVE WINDOW ≈ 160248 °C

NARROWER CUT

Advantages

  • + Higher molecular selectivity
  • + Potentially cleaner jet-range distribution
  • + Reduced heavy-end contamination
  • + Potentially improved downstream upgrading

Trade-offs

  • Lower Jet-RCF yield
  • More material diverted to naphtha and diesel
  • Potential loss of useful boundary molecules

BROADER CUT

Advantages

  • + Higher Jet-RCF recovery
  • + Greater potential volume

Trade-offs

  • Higher heavy/light crossover
  • Potentially poorer freezing behaviour
  • Greater downstream upgrading requirement
  • Potential flash-point / volatility issues

THE OBJECTIVE IS NOT MAXIMUM JET-RCF VOLUME. THE OBJECTIVE IS MAXIMUM VALUE FROM A REFINERY-ACCEPTABLE JET-RANGE FEEDSTOCK.

Provisional Jet-RCF analysis

DEVELOPMENT TARGETS AGAINST RESEARCH REFERENCES.

Where no universal ASTM limit applies to Jet-RCF itself, the figure is labelled as a Green Fuel Tech development target — not an ASTM specification.

ParameterJet-RCF development targetResearch / reference rangeWhy it mattersActual GFT COA
Carbon distributionPredominantly C8–C16Research window C8–C16Core kerosene-range molecular windowPending
Boiling range≈ 150–250 °C initiallyEvaluation potentially extending toward 300 °CControls light/heavy fraction crossoverPending
Density @ 15 °CGFT development evaluation range≈ 0.75–0.84 kg/LEnergy density and hydrocarbon compositionPending
Flash point> 38 °C (GFT development target)Minimum conventional jet-fuel safety benchmarkHandling, storage and transport safetyPending
Final boiling pointGFT development ceiling≤ 300 °C referenceConventional aviation turbine fuel distillation referencePending
10 % recovery temperatureGFT development target≤ 205 °C referenceVolatility / distillation behaviourPending
Freezing pointDevelopment aspiration toward ≤ −47 °CJet A-1 comparison ≤ −47 °CCritical high-altitude operabilityPending
Viscosity @ −20 °CDevelopment aspiration ≤ 8 mm²/sJet A-1 comparison ≤ 8 mm²/sLow-temperature fuel flowPending
Total sulphurGFT development target: progressively reduceJet A-1 comparison ≤ 0.30 mass %Downstream processing and emissionsPending
Mercaptan sulphurGFT development target: minimiseJet A-1 comparison ≤ 0.003 mass %Corrosivity and odourPending
AromaticsGFT development target: characterise and controlJet A-1 comparison ≤ 25 vol %Combustion, seal swell and soot behaviourPending
NitrogenGFT refinery-feedstock target < 500 ppm initiallyStretch target < 100 ppm depending on refinery requirementCatalyst poisoning in downstream hydrotreatmentPending
ChlorineGFT target < 50 ppm initial commercial developmentPreferred refinery target < 10 ppm; stretch as low as practically achievableCorrosion and refinery acceptancePending
WaterGFT target: minimal / refinery acceptableBy refinery agreementPhase separation, corrosion and handlingPending
OxygenGFT target: very low after upgradingBy refinery agreementStability and downstream hydrogen demandPending
OlefinsGFT target: substantially reduced prior to aviation-fuel upgradingBy refinery agreementGum formation and thermal stabilityPending
Acid numberGFT target: low / refinery acceptableBy refinery agreementCorrosivity of the feedstockPending
MetalsGFT target: trace / below customer-specific refinery limitsBy refinery agreementCatalyst protection in downstream unitsPending

Jet A-1 figures are shown only as comparison references for finished aviation turbine fuel. They are not specifications for Jet-RCF. Actual COA values are populated from Green Fuel Tech laboratory results once available.

Visual comparison

BROAD. SELECTED. TIGHTLY CONTROLLED.

From raw pyrolysis oil, through the recovered jet-range fraction, to finished certified aviation fuel.

Expected Jet-RCF recovery

HOW MUCH JET-RCF COULD WE RECOVER?

Published research demonstrates that jet-range recovery from pyrolysis liquids varies dramatically with feedstock, process conditions, cut points and downstream upgrading.

Plastic feedstockPE / PP ratioPyrolysis temperatureResidence timeCatalystCarbon-number distributionDistillation cut pointsReflux ratioUpgradingHydrogenation / hydrotreatingHydrocrackingRecycle strategy

Conservative commercial model

5%

Current Green Fuel Tech financial model

Development case

10%

Process development scenario

Target case

15%

Future optimisation target

Future optimisation target

High jet-range feedstock case

20%

Favourable feedstock and upgrading scenario

% of suitable liquid hydrocarbon feed — Green Fuel Tech modelling scenarios, not guaranteed production yields

Feedstock effect

NOT ALL PLASTIC CREATES THE SAME JET FRACTION.

The molecular distribution of the pyrolysis liquid — and therefore the recoverable jet-range fraction — begins with what enters the reactor.

PP

Potentially favourable for lighter / jet-range hydrocarbons depending on operating conditions.

HDPE

Can generate a broader and heavier hydrocarbon distribution requiring greater fractionation and/or cracking.

LDPE

Potential source of paraffinic hydrocarbon material, but process conditions strongly influence molecular distribution.

PS

Aromatic-rich output. Requires separate consideration for aviation pathways.

PVC

UNDESIRABLE — chlorine contamination risk.

PET

UNDESIRABLE / CONTROLLED — oxygenated compounds and different pyrolysis chemistry.

Mixed plastic

Requires feedstock control and batch analysis.

FEEDSTOCK CONTROL IS THE FIRST STAGE OF FUEL QUALITY.

Capability and limits

WHAT DISTILLATION CAN — AND CANNOT — DO.

Distillation can

  • + Select boiling range
  • + Concentrate C8–C16 molecules
  • + Remove significant light fraction
  • + Remove significant heavy fraction
  • + Improve consistency
  • + Create dedicated product cuts

Distillation cannot fully

  • Remove chlorine
  • Remove nitrogen
  • Remove sulphur
  • Remove all oxygenates
  • Saturate olefins
  • Control aromatic chemistry
  • Guarantee freezing point
  • Create ASTM-compliant SAF

FRACTIONATION SELECTS THE MOLECULES.
UPGRADING IMPROVES THE MOLECULES.
CERTIFICATION QUALIFIES THE FINAL FUEL.

Green Fuel Tech development path

FROM CHARACTERISATION TO COMMERCIAL JET-RCF.

STAGE 1

PPO CHARACTERISATION

  • · GC-MS
  • · Simulated distillation
  • · CHNS
  • · Chlorine
  • · Water
  • · Density
  • · Flash point
STAGE 2

LAB FRACTIONATION

  • · Test cut 150–200 °C
  • · Test cut 200–250 °C
  • · Test cut 250–300 °C
  • · Analyse each fraction
STAGE 3

OPTIMISE JET-RCF CUT

  • · C8–C16 recovery
  • · Flash point
  • · Density
  • · Freezing behaviour
  • · Contaminant profile
  • · Economic yield
STAGE 4

JET-RCF UPGRADING

  • · Guard beds
  • · Contaminant removal
  • · Hydrogenation / hydrotreatment evaluation
  • · Stabilisation
STAGE 5

REFINERY QUALIFICATION

  • · Representative sample
  • · COA
  • · GC×GC / GC-MS
  • · SimDist
  • · Elemental analysis
  • · Contaminant profile
  • · Batch traceability
STAGE 6

COMMERCIAL JET-RCF

  • · Produce against an agreed refinery feedstock specification

Interactive tool

EXPLORE THE FRACTIONATION WINDOW.

Adjust the low and high cut temperatures to see how the window may shift yields, contamination risk and downstream upgrading requirement.

JET-RCF FRACTION ANALYSER

Conceptual engineering model

Selected window

150250 °C

Jet-RCF yield15.6%
Naphtha yield20.0%
Diesel yield37.0%
Light-end contamination risk81
Heavy-end contamination risk43
Freezing-point risk39
Downstream upgrading requirement62
Indicative flash point35 °C

Outputs are directional engineering illustrations only — not Green Fuel Tech laboratory results. The tool is architected so that actual SimDist, GC-MS and batch COA data can be loaded from the production database and drive these estimates directly.

Research insight

WHAT THE PLASTIC-TO-JET LITERATURE INDICATES.

  • Conventional jet fuel is concentrated predominantly around C8–C16 hydrocarbons.
  • Plastic pyrolysis liquids can have much broader distributions extending roughly C2–C40 depending on feedstock and process.
  • Fractional distillation can successfully enrich the jet-range portion.
  • PP may generate a higher proportion of C8–C16 material than HDPE under some pyrolysis conditions.
  • Catalysts and operating conditions can substantially shift jet-range selectivity.
  • Distillation alone does not resolve all aviation-fuel quality requirements.
  • Hydrotreating / hydrogenation and potentially hydroisomerisation may be required downstream.

THIS IS WHY GREEN FUEL TECH POSITIONS JET-RCF AS A REFINERY FEEDSTOCK — NOT DIRECT-TO-AIRCRAFT FUEL.

Jet-RCF process journey

From circular feedstock to a qualified downstream pathway.

The same core Green Fuel Tech process chain — feedstock, preparation, Technotherm pyrolysis, vapour management, condensation, pyrolysis liquid, upgrading, fractionation, quality control — with the jet-range branch highlighted.

Clear jet-range circular hydrocarbon sample in a graduated cylinder in a laboratory
  1. 01

    PLASTIC / SUITABLE CIRCULAR FEEDSTOCK

  2. 02

    PREPARATION

  3. 03

    TECHNOTHERM PYROLYSIS

  4. 04

    HYDROCARBON VAPOURS

  5. 05

    VAPOUR CONDITIONING

  6. 06

    CONDENSATION

  7. 07

    PYROLYSIS OIL

  8. 08

    CONTAMINANT MANAGEMENT

  9. 09

    DEHYDRATION / UPGRADING

  10. 10

    FRACTIONATION

  11. 11

    JET-RANGE CUT

  12. 12

    JET-RCF

  13. 13

    QUALITY ANALYSIS

  14. 14

    DOWNSTREAM REFINERY / SAF PRODUCER

  15. 15

    FURTHER UPGRADING

  16. 16

    POTENTIAL AVIATION FUEL PATHWAY

Downstream refining, hydrotreatment, qualification, blending and certification are carried out by qualified third parties. Green Fuel Tech supplies the circular feedstock fraction.

Product information

Jet-RCF product architecture.

Presented in the same specification-driven structure as every other Green Fuel Tech product.

Product
Jet-RCF
Category
Jet-Range Circular Feedstock
Source
Selected waste-derived hydrocarbon feedstocks processed through the Green Fuel Tech / Technotherm platform.
Process
Pyrolysis → vapour treatment → condensation → upgrading → controlled fractionation.
Product form
Liquid hydrocarbon fraction.
Target market
Downstream refiners, renewable fuel producers, SAF developers and circular hydrocarbon processors.
Potential application
Feedstock for further refining and upgrading toward aviation-fuel-range products.
Commercial basis
Supplied against agreed product specifications and batch Certificate of Analysis.
Traceability
Product traceability is being developed around feedstock origin, production batch, processing route and downstream chain-of-custody requirements.
Certification
ISCC / ISCC PLUS / ISCC EU status: not currently held. Certification status will be published here only once formally obtained.

Product portfolio

ONE FEEDSTOCK. MULTIPLE CIRCULAR PRODUCTS.

Rather than treating the whole pyrolysis liquid as a single commodity, the upgrading strategy recovers the highest-value molecular fractions for their most appropriate downstream markets.

FRACTIONATION COLUMNONE FEEDSTOCK · MULTIPLE CIRCULAR PRODUCTSLIGHTCIRCULAR NAPHTHAJET RANGEJET-RCFMIDDLE DISTILLATECIRCULAR DIESELHEAVIER DISTILLATEMARINE / INDUSTRIAL FUELSOLID RECOVERY FROM TYRESRECOVERED CARBON BLACKMETAL RECOVERY FROM TYRESHIGH-TENSILE STEELENERGYRECOVERED SYNGAS

The commercial objective

RECOVER THE RIGHT MOLECULES.

Green Fuel Tech does not need to become an aviation refinery. The objective is to produce a consistent, traceable, low-contaminant, jet-range circular hydrocarbon feedstock that can be evaluated by downstream refiners and aviation-fuel producers.

ConsistentTraceableLow-contaminantJet-rangeCircular hydrocarbon feedstock
  1. 01

    PLASTIC WASTE

  2. 02

    TECHNOTHERM PYROLYSIS

  3. 03

    GREEN FUEL TECH UPGRADING

  4. 04

    FRACTIONATION

  5. 05

    JET-RCF

  6. 06

    REFINERY

  7. 07

    HYDROTREATING / ADVANCED UPGRADING

  8. 08

    QUALIFICATION

  9. 09

    AVIATION FUEL PATHWAY

WE DON'T NEED TO MAKE THE FINAL JET FUEL.
WE NEED TO RECOVER THE RIGHT MOLECULES.